个人简介

梁作中，男，1990年出生，山东聊城人，中共党员。2011年6月毕业于曲阜师范大学化学与化工学院，获工学学士学位，毕设导师朱万诚教授。2016年6月毕业于北京化工大学化学工程学院，获工学博士学位，导师陈建峰院士。2014年9月-2015年9月，在美国纽约大学化学系进行联合培养，合作导师Bart Kahr教授。2016年7月加入威廉希尔体育app官网，2019年晋升为williamhill威廉希尔官网副研究员，2020年入选“陕西省科协青年人才托举计划”，2022年入选“2023年度陕西省青年科技新星”。

近年来，主要从事新能源电催化领域析氢、析氧、氧还原反应等催化剂的设计、制备及其在电解水、氢燃料电池和金属-空气电池等器件的应用研究。主持国家自然科学基金面上项目、国家自然科学基金青年项目、陕西省重点研发计划、陕西省自然科学基金基础研究计划和中国博士后科学基金（特别资助）等多项。以第一作者或通讯作者在Chem. Soc. Rev.（1篇）、Angew. Chem. Int. Ed.（4篇）、J. Am. Chem. Soc.（1篇）及Chinese Chem. Lett.（3篇）等国内外知名学术期刊上发表论文20余篇，其中，高被引论文3篇，热点论文1篇。

一、主持科研项目

(1) 国家自然科学基金面上项目，22178213，2022.01-2025.12

(2) 陕西省青年科技新星项目，2023KJXX-018，2023.01-2024.12

(3) 陕西省重点研发计划项目，2022GY-196，2022.01-2024.12

(4) 陕西省科协青年人才托举计划项目，20200602，2021.01-2022.12

(5) 国家自然科学基金青年项目，21808138，2019.01-2021.12

(6) 中国博士后科学基金特别资助（站中），2019T120877，2019.01-2020.12

(7) 陕西省自然科学基础研究计划项目，2019JQ-109，2019.01-2020.12

二、代表性论文：

(1) Tang, J.^†;Liang, Z.^†; Qin, H.; Liu, X.; Zhai, B.; Su, Z.; Liu, Q.; Lei, H.; Liu, K.; Zhao, C.^*; Cao, R.^*; Fang, Y.^*, Angew. Chem. Int. Ed. 2023, 62, e202214449.

(2) Liang, Z.^†; Wang, H.-Y.^†; Zheng, H.; Zhang, W.; Cao, R.^*,Chem. Soc. Rev.2021,50, 2540-2581.

(3) Liang, Z.; Kong, N.; Yang, C.; Zhang, W.; Zheng, H.^*; Lin, H.^*; Cao, R.^*,Angew. Chem. Int. Ed.2021,60, 12759-12764.

(4) Liang, Z.; Guo, H.; Zhou, G.; Guo, K.; Wang, B.; Lei, H.; Zhang, W.; Zheng, H.; Apfel, U.-P.; Cao, R.^*,Angew. Chem. Int. Ed.2021,60, 8472-8476.

(5) Cichocka, M. O.^†;Liang, Z.^†; Feng, D.; Back, S.; Siahrostami, S.; Wang, X.; Samperisi, L.; Sun, Y.; Xu, H.; Hedin, N.; Zheng, H.^*; Zou, X.; Zhou, H.-C.^*; Huang, Z.^*,J. Am. Chem. Soc.2020,142, 15386-15395.

(6) Liang, Z.^†; Fan, X.^†; Lei, H.; Qi, J.; Li, Y.; Gao, J.; Huo, M.; Yuan, H.; Zhang, W.; Lin, H.^*; Zheng, H.^*; Cao, R.^*,Angew. Chem. Int. Ed.2018,57, 16593-16593.

三、发表论文列表

2023

(56) Tang, J.^†;Liang, Z.^†; Qin, H.; Liu, X.; Zhai, B.; Su, Z.; Liu, Q.; Lei, H.; Liu, K.; Zhao, C.^*; Cao, R.^*; Fang, Y.^* Large-area Free-standing Metalloporphyrin-based Covalent Organic Framework Films by Liquid-air Interfacial Polymerization for Oxygen Electrocatalysis.Angew. Chem. Int. Ed.2023,62(1), e202214449.

2022

(55) Liang, Z.^*; Guo, H.; Lei, H.; Cao, R.^* Co porphyrin-based metal-organic framework for hydrogen evolution reaction and oxygen reduction reaction.Chin. Chem. Lett.2022,33(8), 3999-4002.

(54) Lei, H.^†; Zhang, Q.^†;Liang, Z.; Guo, H.; Wang, Y.; Lv, H.; Li, X.; Zhang, W.; Apfel, U. P.; Cao, R.^* Metal-Corrole-Based Porous Organic Polymers for Electrocatalytic Oxygen Reduction and Evolution Reactions.Angew. Chem. Int. Ed.2022,61(24), e202201104.

(53) Guo, H.;Liang, Z.; Guo, K.; Lei, H.; Wang, Y.; Zhang, W.; Cao, R.^* Iron porphyrin with appended guanidyl group for significantly improved electrocatalytic carbon dioxide reduction activity and selectivity in aqueous solutions.Chin. J. Catal.2022,43(12), 3089-3094.

(52) Liu, T.; Zhang, Q.; Guo, H.;Liang, Z.; Cao, R.^* Electrocatalytic oxygen reduction reaction with metalloporphyrins.Sci. Sin.: Chim2022,52(8), 1306-1320.

(51) Bao, Z.; Wang, Y.; Shi, M.; Wang, X.;Liang, Z.; Huang, Z.; Zhang, W.; Cao, R.; Zheng, H.^* A helical polypyrrole nanotube interwoven zeolitic imidazolate framework and its derivative as an oxygen electrocatalyst.Chem. Commun.2022,58(80), 11288-11291.

(50) Wang, Y.; Sun, T.; Mostaghimi, A. H. B.; Goncalves, T. J.;Liang, Z.; Zhou, Y.; Zhang, W.; Huang, Z.; Ma, Y.; Cao, R.; Siahrostami, S.^*; Zheng, H.^* Two-Dimensional Metal–Organic Frameworks with Unique Oriented Layers for Oxygen Reduction Reaction: Tailoring the Activity through Exposed Crystal Facets.CCS Chemistry2022,4(5), 1633-1642.

(49) Wang, Y.^*; Suo, W.; Huang, Y.; Zhang, M.; Lai, X.;Liang, Z.; Li, Z.^* Defect structure regulation and mass transfer improvement of cobalt-based oxides for enhanced oxygen evolution reaction.J. Alloys Compd.2022,928, 167210.

(48) Guo, H.^†; Wang, Y.; Guo, K.; Lei, H.;Liang, Z.^*; Zhang, X.-P.^*; Cao, R.^* A Co Porphyrin with Electron-Withdrawing and Hydrophilic Substituents for Improved Electrocatalytic Oxygen Reduction.J. Electrochem.2022,28(9), 2214002.

2021

(47) Liang, Z.^†; Wang, H.-Y.^†; Zheng, H.; Zhang, W.; Cao, R.^*, Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide.Chem. Soc. Rev.2021,50, 2540-2581.

(46) Liang, Z.; Kong, N.; Yang, C.; Zhang, W.; Zheng, H.^*; Lin, H.^*; Cao, R.^*, Highly Curved Nanostructure-Coated Co, N-Doped Carbon Materials for Oxygen Electrocatalysis.Angew. Chem. Int. Ed.2021,60, 12759-12764.

(45) Liang, Z.; Guo, H.; Zhou, G.; Guo, K.; Wang, B.; Lei, H.; Zhang, W.; Zheng, H.; Apfel, U.-P.; Cao, R.^*, Metal-Organic-Framework-Supported Molecular Electrocatalysis for the Oxygen Reduction Reaction.Angew. Chem. Int. Ed.2021,60, 8472-8476.

(44) Liang, Z.; Yang, C; Zhang, W.; Zheng, H.^*; Cao, R.^*; Anion engineering of hierarchical Co-A (A= O, Se, P) hexagrams for efficient electrocatalytic oxygen evolution reaction.Chin. Chem. Lett.2021,32, 3241-3244.

(43) Wang, Y.; Wang, B.; Yuan, H.;Liang, Z.; Huang, Z.; Zhou, Y.; Zhang, W.; Zheng, H.^*; Cao, R.^*, Inherent mass transfer engineering of a Co, N co-doped carbon material towards oxygen reduction reaction.J. Energy Chem.2021,58, 391-396.

(42) Wang, Y.; Bao, Z.; Shi, M.;Liang, Z.; Cao, R.; Zheng, H.^*, The Role of Surface Curvature in Electrocatalysts.Chem. Eur. J.2021, DOI: 10.1002/chem.202102915.

(41) Wang, F.; Xu, Y.; Wang, Y.;Liang, Z.; Zhang, R.; Wang, Y.; Zhang, H.; Zhang, W.; Cao, R.; Zheng, H.^*, Space-confined construction of two-dimensional nitrogen-doped carbon with encapsulated bimetallic nanoparticles as oxygen electrocatalysts.Chem. Commun.2021,57, 8190-8193.

(40) Lei, H.; Zhang, Q.; Wang, Y.; Gao, Y.; Wang, Y.;Liang, Z.; Zhang, W.; Cao, R.^*, Significantly boosted oxygen electrocatalysis with cooperation between cobalt and iron porphyrins dagger.Dalton Trans.2021,50, 5120-5123.

(39) Jia, X.; Li, S.; Sun, T.; Wang, Y.; Fan, Y.; Zhang, C.; Xu, Y.;Liang, Z.; Lei, H.; Zhang, W.; Zhou, Y.; Ma, Y.; Zheng, H.^*; Ma, Y.^*; Cao, R.^*, Single crystal metal-organic framework constructed by vertically self-pillared nanosheets and its derivative for oriented lithium plating.Chin. J. Catal.2021,42, 1553-1560.

(38) Lv, H.; Guo, H.; Guo, K.; Lei, H.; Zhang, W.; Zheng, H.;Liang, Z.^*; Cao, R.^*, Substituent position effect of Co porphyrin on oxygen electrocatalysis.Chin. Chem. Lett.2021,32, 2841-2845.

2020

(37) Liang, Z.; Zheng, H.^*; Cao, R.^*, Recent advances in Co-based electrocatalysts for the oxygen reduction reaction.Sustain. Energy Fuels2020,4, 3848-3870.

(36) Cichocka, M. O.^†;Liang, Z.^†; Feng, D.; Back, S.; Siahrostami, S.; Wang, X.; Samperisi, L.; Sun, Y.; Xu, H.; Hedin, N.; Zheng, H.^*; Zou, X.; Zhou, H.-C.^*; Huang, Z.^*, A Porphyrinic Zirconium Metal-Organic Framework for Oxygen Reduction Reaction: Tailoring the Spacing between Active-Sites through Chain-Based Inorganic Building Units.J. Am. Chem. Soc.2020,142, 15386-15395.

(35) Wang, Y.; Yang, C.; Huang, Y.; Li, Z.^*;Liang, Z.^*; Cao, G.^*, Nickel induced electronic structural regulation of cobalt hydroxide for enhanced water oxidation.J. Mater. Chem. A2020,8, 6699-6708.

(34) Wang, Y.;Liang, Z.; Zheng, H.^*; Cao, R.^*, Recent Progress on Defect-rich Transition Metal Oxides and Their Energy-Related Applications.Chem-Asian J2020,15, 3717-3736.

(33) Lv, H.; Xu, D.; Kong, C.;Liang, Z.; Zheng, H.; Huang, Z.^*; Liu, B.^*, Synthesis and Crystal-Phase Engineering of Mesoporous Palladium-Boron Alloy Nanoparticles.ACS Central Science2020,6, 2347-2353.

(32) Zhang, C.; Yang, H.; Zhong, D.; Xu, Y.; Wang, Y.; Yuan, Q.;Liang, Z.; Wang, B.; Zhang, W.; Zheng, H.^*; Cheng, T.^*; Cao, R.^*, A yolk-shell structured metal-organic framework with encapsulated iron-porphyrin and its derived bimetallic nitrogen-doped porous carbon for an efficient oxygen reduction reaction.J. Mater. Chem. A2020,8, 9536-9544.

(31) Wang, Y.; Yang, C.; Li, Z.^*;Liang, Z.^*; Cao, G.^*, The -NHx Group Induced Formation of 3D alpha-Co(OH)(2) Curly Nanosheet Aggregates as Efficient Oxygen Evolution Electrocatalysts.Small2020,16,2001973.

2019

(30) Liang, Z.; Zheng, H.^*; Cao, R.^*, Importance of Electrocatalyst Morphology for the Oxygen Reduction Reaction.ChemElectroChem2019,6, 2600-2614.

(29) Liang, Z.; Zhang, C.; Xu, Y.; Zhang, W.; Zheng, H.^*; Cao, R.^*, Dual Tuning of Ultrathin alpha-Co(OH)(2) Nanosheets by Solvent Engineering and Coordination Competition for Efficient Oxygen Evolution.ACS Sustainable Chem. Eng.2019,7, 3527-3535.

(28) Liang, Z.; Yang, Z.; Dang, J.; Qi, J.; Yuan, H.; Gao, J.; Zhang, W.; Zheng, H.^*; Cao, R.^*, Hollow Bimetallic Zinc Cobalt Phosphosulfides for Efficient Overall Water Splitting.Chem. Eur. J.2019,25, 621-626.

(27) Zhang, Y.; Chen, Y.;Liang, Z.; Qi, J.; Gao, X.; Zhang, W.^*; Cao, R.^*, Controlled synthesis of hexagonal annular Mn(OH)F for water oxidation.Chin. J. Catal.2019,40, 1860-1866.

(26) Yuan, H.; Wang, Y.; Yang, C.;Liang, Z.; Chen, M.; Zhang, W.; Zheng, H.^*; Cao, R.^*, Ultra-thin Co-Fe Layered Double Hydroxide Hollow Nanocubes for Efficient Electrocatalytic Water Oxidation.ChemPhysChem2019,20, 2964-2967.

(25) Xu, Y.; Huang, Z.; Wang, B.;Liang, Z.; Zhang, C.; Wang, Y.; Zhang, W.; Zheng, H.^*; Cao, R.^*, A two-dimensional multi-shelled metal-organic framework and its derived bimetallic N-doped porous carbon for electrocatalytic oxygen reduction.Chem. Commun.2019,55, 14805-14808.

(24) Huo, M.; Yang, Z.; Yang, C.; Gao, Z.; Qi, J.;Liang, Z.; Liu, K.; Chen, H.; Zheng, H.^*; Cao, R.^*, Hierarchical Zn-Doped CoO Nanoflowers for Electrocatalytic Oxygen Evolution Reaction.ChemCatChem2019,11, 1480-1486.

(23) Huo, M.; Wang, B.; Zhang, C.; Ding, S.; Yuan, H.;Liang, Z.; Qi, J.; Chen, M.; Xu, Y.; Zhang, W.; Zheng, H.^*; Cao, R.^*, 2D Metal-Organic Framework Derived CuCo Alloy Nanoparticles Encapsulated by Nitrogen-Doped Carbonaceous Nanoleaves for Efficient Bifunctional Oxygen Electrocatalyst and Zinc-Air Batteries.Chem. Eur. J.2019,25, 12780-12788.

2018

(22) Liang, Z.^†; Fan, X.^†; Lei, H.; Qi, J.; Li, Y.; Gao, J.; Huo, M.; Yuan, H.; Zhang, W.; Lin, H.^*; Zheng, H.^*; Cao, R.^*, Cobalt-Nitrogen-Doped Helical Carbonaceous Nanotubes as a Class of Efficient Electrocatalysts for the Oxygen Reduction Reaction.Angew. Chem. Int. Ed.2018,57, 13187-13191.

(21) Liang, Z.; Zhang, C.; Yuan, H.; Zhang, W.; Zheng, H.^*; Cao, R.^*, PVP-assisted transformation of a metal-organic framework into Co-embedded N-enriched meso/microporous carbon materials as bifunctional electrocatalysts.Chem. Commun.2018,54, 7519-7522.

(20) Liang, Z.; Yang, Z.; Yuan, H.; Wang, C.; Qi, J.; Liu, K.; Cao, R.; Zheng, H.^*, A protein@metal-organic framework nanocomposite for pH-triggered anticancer drug delivery.Dalton Trans.2018,47, 10223-10228.

(19) Liang, Z.; Yang, Z.; Huang, Z.; Qi, J.; Chen, M.; Zhang, W.; Zheng, H.^*; Sun, J.; Cao, R.^*, Novel insight into the epitaxial growth mechanism of six-fold symmetrical beta-Co(OH)(2)/Co(OH)F hierarchical hexagrams and their water oxidation activity.Electrochim. Acta2018,271, 526-536.

(18) Liang, Z.; Huang, Z.; Yuan, H.; Yang, Z.; Zhang, C.; Xu, Y.; Zhang, W.; Zheng, H.^*; Cao, R.^*, Quasi-single-crystalline CoO hexagrams with abundant defects for highly efficient electrocatalytic water oxidation.Chem. Sci.2018,9, 6961-6968.

(17) Yan, K.;Liang, Z.; Li, Z.; Zhang, M.; Huang, Y.; Wang, Y.^*, HMTA-assisted formation of hierarchical Co-based materials built by low-dimensional substructures as water oxidation electrocatalysts.CrystEngComm2018,20, 5249-5255.

(16) Lei, H.; Chen, M.;Liang, Z.; Liu, C.; Zhang, W.; Cao, R.^*, Ni₂P hollow microspheres for electrocatalytic oxygen evolution and reduction reactions.Catal. Sci. Technol.2018,8, 2289-2293.

(15) Jia, X.; Yang, Z.; Wang, Y.; Chen, Y.; Yuan, H.; Chen, H.; Xu, X.; Gao, X.;Liang, Z.; Sun, Y.; Li, J.-R.; Zheng, H.^*; Cao, R.^*, Hollow Mesoporous Silica@Metal-Organic Framework and Applications for pH-Responsive Drug Delivery.ChemMedChem2018,13, 400-405.

2017

(14) Liang, Z.; Wang, W.; Zhang, M.; Wu, F.; Chen, J.-F.; Xue, C.^*; Zhao, H.^*, Structural, mechanical and thermodynamic properties of ZrO₂polymorphs by first-principles calculation.Physica B-Condensed Matter2017,511, 10-19.

(13) Liang, Z.; Zhang, M.; Wu, F.; Chen, J.-F.; Xue, C.^*; Zhao, H.^*, Supersaturation controlled morphology and aspect ratio changes of benzoic acid crystals.Comput. Chem. Eng.2017,99, 296-303.

(12) Wang, Y.;Liang, Z.^*, Solvent effects and its role in quantitatively manipulating the crystal growth: benzoic acid as case study.CrystEngComm2017,19, 3198-3205.

(11) Wang, Y.;Liang, Z.^*, Growth mechanism study of clustered aggregates of dirithromycin crystals in N, N-dimethylformamide solvent.CrystEngComm2017,19, 5583-5590.

(10) Wang, Y.;Liang, Z.^*, Solvent effects on the crystal growth structure and morphology of the pharmaceutical dirithromycin.J. Cryst. Growth2017,480, 18-27.

(9) Zhang, L.^*; Wu, S.;Liang, Z.; Zhao, H.; Zou, H.; Chu, G., Hydrogen sulfide removal by catalytic oxidative absorption method using rotating packed bed reactor.Chin. J. Chem. Eng.2017,25, 175-179.

(8) Zhang, M.;Liang, Z.; Wu, F.; Chen, J.-F.; Xue, C.^*; Zhao, H.^*, Crystal engineering of ibuprofen compounds: From molecule to crystal structure to morphology prediction by computational simulation and experimental study.J. Cryst. Growth2017,467, 47-53.

2016 and before

(7) Wang, W.;Liang, Z.; Han, X.; Chen, J.; Xue, C.^*; Zhao, H.^*, Mechanical and thermodynamic properties of ZrO₂under high-pressure phase transition: A first-principles study.J. Alloys Compd.2015,622, 504-512.

(6) Liang, Z.; Wang, Y.; Wang, W.; Han, X.; Chen, J.-F.^*; Xue, C.^*; Zhao, H.^*, Structural Correspondence of the Oriented Attachment Growth Mechanism of Crystals of the Pharmaceutical Dirithromycin.Langmuir2015,31, 13802-13812.

(5) Liang, Z.; Wang, W.; Han, X.; Liu, J.; Chen, J.; Chu, G.; Zou, H.; Zhao, H.^*, Experimental research on hydrogen sulfide removal by high gravity technology with iron-based desulfurizer.Chem. Ind. Eng. Pro.2015,34, 2065-2069.

(4) Han, X.;Liang, Z.; Wang, W.; Chen, J.; Xue, C.^*; Zhao, H.^*, Characterization and synthesis of ZTA nanopowders and ceramics by rotating packed bed (RPB).Ceram. Int.2015,41, 3568-3573.

(3) Han, X.;Liang, Z.; Feng, L.; Wang, W.; Chen, J.; Xue, C.^*; Zhao, H.^*, Co-precipitated synthesis of Al₂O₃-ZrO₂composite ceramic nanopowders by precipitant and drying method regulation: A systematic study.Ceram. Int.2015,41, 505-513.

(2) Liang, Z.; Chen, J.-F.; Ma, Y.; Wang, W.; Han, X.; Xue, C.^*; Zhao, H.^*, Qualitative rationalization of the crystal growth morphology of benzoic acid controlled using solvents.CrystEngComm2014,16, 5997-6002.

(1) Zhu, W.^*;Liang, Z.; Liu, X.; Zhang, H.; Zheng, Y.; Piao, X.; Zhang, Q.^*, Soft-template self-assembly of hierarchical mesoporous SrCO₃by low-temperature hydrothermal route and their application as adsorbents for methylene blue and heavy metal ions.Powder Technol.2012,226, 165-172.

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