个人简介
2008年12月份获得工学博士学位,2011年10月至2013年8月,在加拿大麦吉尔大学做访问教授。主要从事高效串联反应、H2O2 选择性氧化等绿色催化合成方面的研究工作,在环境友好反应介质绿色过程替代等方面具有较好的研究积累。目前主持国家自然科学基金面上项目1项、国家重点研发计划子课题1项、williamhill威廉希尔官网中央高校基本科研业务费科研发展专项1项,参与国家自然科学基金重点项目一项(第二参与人)。主持完成国家自然科学基金2项、陕西省自然科学基金、西安市工业应用技术研究项目等7 项。在 J. Am. Chem. Soc.、Angew Chem. Int. Ed.、Org. Lett.、Adv. Synth. Catal.、Chem.Eur. J.、J. Org. Chem. 等本领域主流学术期刊发表研究论文50 余篇,申请中国发明专利10件,其中授权5 件,获陕西省高等学校科学技术奖一等奖(2016 年,第二完成人)和陕西省科学技术奖二等奖(2016 年,第二完成人)。参编《有机化学学习指导与习题详解》和《中级有机化学》,编著《过渡金属催化的碳氢键官能团化反应》。研究兴趣:(1) 过氧化氢为氧源的绿色催化氧化反应;(2)过渡金属催化碳氢键活化的高效串联反应。
代表性成果
1. Jia-Ni Wang, Si-Qi Chen, Zhong-Wen Liu, Xian-Ying Shi*, Divergent syntheses of spiroindanones and 2‑substituted 1‑indanones by ruthenium-catalyzed tandem coupling and cyclization of aromatic acids with α,β-unsaturated ketones, J. Org. Chem., 2019, 84, 1348−1362.
2. Wen-Jing Han, Fan Pu, Chao-Jun Li, Zhong-Wen Liu, Juan Fan, Xian-Ying Shi*, Carboxyl-directed conjugate addition of C-H bonds to α,β-unsaturated ketones in air and water, Adv. Synth. Catal., 2018, 360, 1358−1363.
3. Fan Pu, Lin-Yan Zhang, Zhong-Wen Liu, Xian-Ying Shi*, Palladium(II)-catalyzed decarboxylative cross-dehydrogenative coupling: direct synthesis of meta-substituted biaryls from aromatic acids, Adv. Synth. Catal., 2018, 360, 2644−2649.
4. Juan Fan, Peng-Min Wang, Jia-Ni Wang, Xue Zhao, Zhong-Wen Liu, Jun-Fa Wei & Xian-Ying Shi*, Ruthenium (II)-catalyzed synthesis of phthalides via the cascade addition and cyclization of aromatic acids with aldehydes, Sci. China Chem., 2018, 61, 153−158.
5. Wen-Jing Han, Fan Pu, Juan Fan, Zhong-Wen Liu, Xian-Ying Shi*, Rhodium(III)-catalyzed tandem C−H olefination and oxidative cyclization of aromatic acids with acrylates for the synthesis of (E)-3- ylidenephthalides, Adv. Synth. Catal., 2017, 359, 3520−3525
6. Peng-Min Wang, Fan Pu, Ke-Yan Liu, Chao-Jun Li, Zhong-Wen Liu, Xian-Ying Shi*, Juan Fan, Ming-Yu Yang, Jun-Fa Wei, Catalyst-free three-component tandem CDC cyclization: convenient access to isoindolinones from aromatic acid, amides, and DMSO by a pummerer-type rearrangement, Chem. Eur. J., 2016, 22, 6262−6267.
7. Xian-Ying Shi*, Wen-Jing Han, Chao-Jun Li*, Transition-metal-catalyzed direct addition of aryl C–H bonds to unsaturated electrophiles, Chem. Rec., 2016, 16, 1178−1190.
8. Juan Fan, Fan Pu, Man Sun, Zhong-Wen Liu, Xiao-Yan Han, Jun-Fa Wei, Xian-Ying Shi*, Immobilized bis-layered ionic liquids/peroxotungstates as an efficient catalyst for selective oxidation of alcohols in neat water, New J. Chem., 2016, 40, 10498−10503.
9. Xian-Ying Shi*, Ke-Yan Liu, Juan Fan, Xue-Fen Dong, Jun-Fa Wei, Chao-Jun Li*, A convenient synthesis of N-aryl benzamides by rhodium-catalyzed ortho-amidation and decarboxylation of benzoic acids, Chem. Eur. J., 2015, 21, 1900−1903.
10. Xian-Ying Shi*, Man Sun, Juan Fan, Peng-Min Wang, Wen-Juan Ma, Jun-Fa Wei*, Deep oxidative desulfurization of benzothiophene and dibenzothiophene with a peroxophosphotungstate–ionic liquid brush assembly, Appl. Organometal. Chem., 2015, 29, 633−637.
11. Xian-Ying Shi*, Xue-Fen Dong, Juan Fan, Ke-Yan Liu, Jun-Fa Wei, Chao-Jun Li*, Ru(II)-catalyzed ortho-amidation and decarboxylation of aromatic acids: a versatile route to meta-substituted N-aryl benzamides, Sci. China. Chem., 2015, 58, 1286−1291.