个人简介

2014/9 -至今，williamhill威廉希尔官网，威廉希尔体育app官网，研究员

研究课题：廉价金属催化的自由基反应

2011/3 - 2014/9，南弗罗里达大学，化学系，博士后

研究课题：新的手性二价钴卟啉合成及应用于自由基途径的不对称C（sp3）-H键的胺化

2010/3 - 2011/3，加州大学圣芭芭拉分校化学系，博士后

研究课题：金催化的氮杂环的合成，及不饱和酮，亚胺的合成

2005/9 - 2010/7，利物浦大学，有机化学，博士，导师：肖建良

研究课题：不对称氢化高立体选择性合成手性胺研究

2000/7 - 2005/7，中国科学院上海有机所，化学系，研究助手

研究课题：路易士碱催化的Baylis-Hillman反应及药物中间体的合成

代表性成果

[1].Hongjian Lu*,Chaoqun Li, Huiling Jiang, Lizardi, C. L.,Zhang, X. Peter* “Chemoselective Amination of PropargylicC(sp3)−H Bonds via Co(II)-Based Metalloradical Catalysis”Angew. Chem. Int. Ed. Engl.2014, 53, 7028-7032.

[2].Weijun Tang, Johnston S.,Chaoqun Li, Iggo, J.,Bacsa, J.,Jianliang Xiao* “Cooperative Catalysis: Combining an Achiral Metal Catalyst with a Chiral Brønsted Acid Enables Highly Enantioselective Hydrogenation of Imines ”Chem. Eur. J.2013, 19, 14187-14193.

[3].Chaoqun Li, Liming Zhang * “Gold-Catalyzed Nitrene Transfer to Activated Alkynes: Formation of α, β-Unsaturated Amidines”Org. Lett.2011, 13, 1378-1741.

[4].Weiming He，Chaoqun Li, Liming Zhang *“An Efficient [2 + 2 + 1] Synthesis of 2,5-Disubstituted Oxazoles via Gold-Catalyzed Intermolecular Alkyne Oxidation”J. Am. Chem. Soc.2011, 133, 8482-8485.

[5].Biao Lu,Chaoqun Li,Liming Zhang* “Gold-Catalyzed Highly Regioselective Oxidation of C-C Triple Bonds without Acid Additives: Propargyl Moieties as Masked α, β-Unsaturated Carbonyls”J. Am. Chem. Soc. 2010, 132, 14070-14072.

[6]. Li Cui,Chaoqun Li,Liming Zhang * “A Modular, Efficient, and Stereoselective Synthesis of Substituted Piperidin-4-ols”Angew. Chem. Int. Ed. Engl.2010, 49, 9178-9181.

[7].Chaoqun Li,Barbara Villa-Marcos, Jianliang Xiao* “Metal-Bronsted Acid Cooperative Catalysis for Asymmetric Reductive Amination”J. Am. Chem. Soc. 2009, 131, 6967-6969.

[8]. Chao Wang,Chaoqun Li, Xiaofeng Wu, Alan Pettman,Jianliang Xiao* “pH-Regulated Asymmetric Transfer Hydrogenation of Quinolines in Water”Angew. Chem. Int. Ed. Engl. 2009, 48, 6524-6528.

[9].Chaoqun Li,Chao Wang, Barbara Villa-Marcos, Jianliang Xiao* “Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines”J. Am. Chem. Soc. 2008, 130, 14450-14451.

[10].Chaoqun Li,Jianliang Xiao* “Asymmetric Hydrogenation of Cyclic Imines with an Ionic Cp*Rh(III) Catalyst”J. Am. Chem. Soc. 2008, 130, 13208.

[11]. Min Shi*, Lianhui Chen,Chaoqun Li,“Chiral Phosphine Lewis Bases Catalyzed Asymmetric aza-Baylis-Hillman Reaction of N-Sulfonated Imines with Activated Olefins”J. Am. Chem. Soc.2005, 127, 127, 3790-3800.