个人简介
张伟强,教授,无机化学教研室主任,主讲本科生课程《无机化学》《金属有机化学,中英双语》,硕士研究生课程《高等无机化学》《无机合成化学及催化应用》,博士研究生课程《Synthetic Chemistry》。1998年本科毕业于西北大学化学系有机合成专业,后保送至中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室(OSSO)攻读博士。博士期间,师从殷元骐研究员从事过渡金属羰基化簇合物的合成、表征与催化性能研究。2002年博士毕业后,加入中科院上海有机所金属有机国家重点实验室邓敏智研究员小组进行博士后研究,从事钯催化硼酸羰基化研究。2005-2010年,博士后留学英美五年,主要从事过渡金属羰基配合物设计合成及一氧化碳缓释治疗研究。2010年回国入职威廉希尔体育app官网,开始独立科研工作。我们课题组长期专注金属羰基配位化学相关研究,分别在治疗型一氧化碳释放分子、钯催化碳碳键偶联、羰基化反应等方面取得一系列进展。先后承担完成国家自然科学基金面上项目2项、陕西省自然科学基金项目2项,相关研究发表研究论文50余篇,申请中国发明专利18个,获2019年陕西省自然科学奖(排名第二)。
代表性成果
1) Zhuangli Zhu, Zhenhua Wang, Yajun Jian, Huaming Sun, Guofang Zhang, Jason M. Lynam, C. Robert McElroy, Thomas J. Burden, Rebecca L. Inight, Ian J. S. Fairlamb*,Weiqiang Zhang *, Ziwei Gao *,Pd-Catalysed carbonylative Suzuki–Miyaura cross-couplings using Fe(CO)5 under mild conditions: generation of a highly active, recyclable and scalable ‘Pd–Fe’ nanocatalyst, Green Chem.,2021, 23, 920-926.
2) Yanyan Wang, Jiaping Liao, Zunyuan Xie, Kan Zhang, Ya Wu, Ping Zuo,Weiqiang Zhang*, Jiyang Li*, Ziwei Gao*. Zeolite-enhanced sustainable Pd catalyzed C-C cross-coupling reaction: controlled release and capture of palladium. ACS Applied Materials & Interfaces, 2020, 12, 11419−11427.
3) Peisen Gao, Kan Zhang, Mingming Yang, Shan Xu, Huaming Sun, Jinlei Zhang, Ziwei Gao*,Weiqiang Zhang*, Liwen Xu*, A robust multifunctional ligand-controlled palladium-catalyzed carbonylation reaction in water, Chem. Comm. 2018,54, 5074-5077.
4) Shan Xu, Huaming Sun, Mengyuan Zhuang, Shaohua Zheng, Yajun Jian,Weiqiang Zhang*, Ziwei Gao*, Divergent synthesis of flavones and aurones via base-controlled regioselective palladium catalyzed carbonylative cyclization,Mol. Catal. 2018, 452, 24-29
5) Shuhong Yang, Mengjiao Chen, Lingling Zhou, Guofang Zhang, Ziwei Gao,Weiqiang Zhang*, Photo-activated CO-releasing molecules (PhotoCORMs) of robust sawhorse scaffolds,Dalton Trans.,2016, 45, 3727–3733.
6) Bo Yu, Huaming Sun, Zunyuan Xie, Guofang Zhang, Liwen Xu,Weiqiang Zhang*, Ziwei Gao*, Privilege Ynone Synthesis via Palladium-Catalyzed Alkynylation of "Super-Active Esters".Org. Lett., 2015, 17, 3298-3301.
7) Wei Xu, Huaming Sun, Bo Yu, Guofang Zhang,Weiqiang Zhang*, Ziwei Gao*, Sonogashira Couplings on the Surface of Montmorillonite Supported Pd/Cu Nanoalloys,ACS Appl. Mater. Interfaces,2014, 6, 20261-20268.
8)Weiqiang Zhang, A. J. Atkin, A. C. Wood, I. J. S. Fairlamb,J. M. Lynam*,Synthesis and Reactivity of Molybdenum Complexes Containing Functionalized Alkynyl Ligands: A Photochemically Activated CO-Releasing Molecule (PhotoCO-RM), Organometallics,2011, 30(11), 4643-4654.
9)Weiqiang Zhang, A. C. Wood, I. J. S. Fairlamb and J. M. Lynam*. "Group 6 Carbon Monoxide-Releasing Metal Complexes with Biologically-Compatible Leaving Groups."Inorg. Chem.,2010, 49(19), 8941-8952.
10)Weiqiang Zhang, A. J. Atkin, R. J. Thatcher, A. C. Whitwood, I. J. S. Fairlamb, J. M. Lynam*,Diversity and design of metal-based carbon monoxide-releasing molecules (CO-RMs) in aqueous systems: revealing the essential trends,Dalton Trans.,2009, 38(22), 4351-4358.